It's the menthol. Two teams
of researchers (one at the University of California and another
at the Scripps Research Institute) studied how menthol makes your
mouth feel "cool". They discovered that what makes chili
peppers seem hot, makes menthol feel cold–it comes down to
microscopic cell receptors. The teams called the receptor two different
names, we'll go with CMR1 (Cold Menthol Receptor Type 1) because
it includes menthol in the name.
The CMR1 receptor is activated within a range of temperatures–between
8 and 28 degrees Celsius. When exposed to these temperatures, the
receptor lets large amounts of calcium atoms into the cell, which
causes another set of reactions. The same receptor, it turns out,
is also activated by menthol–tricking you into thinking it
is "cool".
There are two other receptors (which are in the same protein family
as CMR1) identified by scientists: VR1 for hot, and VRL1 for super
hot. Think hot chili peppers. VR1 covers temperatures greater than
43 degrees Celsius and VRL-1 covers temperatures greater than 50
degrees Celsius. So what about receptors to identify temperatures
between 28 and 43 degrees? Researchers, somewhere, are working on
that.